One of the problems in trying to devise a system for running a
hydrogen fuel cell is exactly how to store the stuff-it leaks out
of normal pressurised containers fairly easily. Researchers have
devised chemical sponges to try and trap the atoms but so far
cannot get the density per liter desired to be able to
practically use fuel storage containers for vehicles. A new
technique has looked at the actual size of the chemicals used to
hold and trap the hydrogen, and they think they now know
what that size is and can get good storage densities.
"University of Nottingham scientists have made a
breakthrough which could help in the development of the next
generation of environmentally-friendly cars. Their
latest findings on hydrogen storage could be crucial in the
development of hydrogen-powered vehicles that are a viable
alternative to the petrol and diesel-powered vehicles of
today."..more cage the tiny tiger there
One of the many reasons why I think the "hydrogen economy" is a red herring.
Long-chain carbon is where it's at. Butanol, bio-diesel, etc. There just isn't enough energy density in hydrogen, even though it's sexy and "hollywood"....
Long-chain carbon (bio-diesel, various forms of alcohol, such as butanol) works smoothly and efficiently using the same distribution network we've put together to deal with fossil fuels. Better - these fuels are interchangeable! You can mix butanol with gasoline and barely tell the difference. You can mix biodiesel with fossil diesel and barely tell the difference.
Contrast that with hydrogen, which requires a major rework of the entire energy distribution system. See a problem?
I sure do.
The future is long-chain carbon. The distraction is the "hydrogen economy" - designed to keep us using fossil fuels as long as possible.
It approaches the DoE target of storing 45 grams per liter. In a tank the size of my car's gas tank, that would be two kilograms of hydrogen. 280+ megajoules theoretical energy capacity. Same volume of gasoline, almost 1500.
A fuel cell is roughly twice as efficient as an internal combustion engine, but we're still looking at an issue here. Wait, maybe not: you can triple the volume of the gas tank by making it 1.44 times larger in each direction.
Anhydrous ammonia in liquid form has a hydrogen density of 146 grams/liter, and is easily "reformed" for fuel cell use. The only reason it isn't being suggested as a means of hydrogen storage is that it (ammonia) is well understood as a substance, and storage implications are also well known, i.e., no grant money.
Finding the Sweet Spot for Hydrogen Storage
One of the problems in trying to devise a system for running a hydrogen fuel cell is exactly how to store the stuff-it leaks out of normal pressurised containers fairly easily. Researchers have devised chemical sponges to try and trap the atoms but so far cannot get the density per liter desired to be able to practically use fuel storage containers for vehicles. A new technique has looked at the actual size of the chemicals used to hold and trap the hydrogen, and they think they now know what that size is and can get good storage densities.
"University of Nottingham scientists have made a breakthrough which could help in the development of the next generation of environmentally-friendly cars. Their latest findings on hydrogen storage could be crucial in the development of hydrogen-powered vehicles that are a viable alternative to the petrol and diesel-powered vehicles of today."..more cage the tiny tiger there